GeTe2 Phase Change Material for Terahertz Devices with Reconfigurable Functionalities Using Optical Activation.

The phenomenon of phase change transition has been a fascinating research subject over decades due to a possibility of dynamically controlled materials properties, allowing the creation of optical devices with unique features. The present paper unravels the optical characteristics and terahertz (THz) dielectric permittivity of a novel phase change material (PCM), GeTe2, prepared by pulsed laser deposition (PLD) and their remarkable contrast in crystalline and amorphous states, in particular, a difference of 7 orders of magnitude in conductivity. The THz spectra were analyzed using the harmonic oscillator and Drude term. Using GeTe2 PLD films, we designed and prepared a THz metasurface in the form of periodic structure and revealed a possibility of tuning the THz resonance either by a thermal control or light-induced crystallization response, thus achieving the dynamic and tunable functionality of the metastructure. We propose controlling the state of metasurface by observing the intensity characteristics of the Raman peak of 155 cm-1. Density functional theory (DFT) modeling demonstrates that in the process of crystallization the mode intensity of 155 cm-1 assigned to Te-Te stretching in amorphous chain fragments decreases and disappears at full crystallization.

Label-free laser spectroscopy for respiratory virus detection: A review.

Infectious diseases are among the most severe threats to modern society. Current methods of virus infection detection based on genome tests need reagents and specialized laboratories. The desired characteristics of new virus detection methods are noninvasiveness, simplicity of implementation, real-time, low cost and label-free detection. There are two groups of methods for molecular biomarkers' detection and analysis: (i) a sample physical separation into individual molecular components and their identification, and (ii) sample content analysis by laser spectroscopy. Variations in the spectral data are typically minor. It requires the use of sophisticated analytical methods like machine learning. This review examines the current technological level of laser spectroscopy and machine learning methods in applications for virus infection detection.

Photoinduced large polaron transport and dynamics in organic-inorganic hybrid lead halide perovskite with terahertz probes.

Organic-inorganic hybrid metal halide perovskites (MHPs) have attracted tremendous attention for optoelectronic applications. The long photocarrier lifetime and moderate carrier mobility have been proposed as results of the large polaron formation in MHPs. However, it is challenging to measure the effective mass and carrier scattering parameters of the photogenerated large polarons in the ultrafast carrier recombination dynamics. Here, we show, in a one-step spectroscopic method, that the optical-pump and terahertz-electromagnetic probe (OPTP) technique allows us to access the nature of interplay of photoexcited unbound charge carriers and optical phonons in polycrystalline CH3NH3PbI3 (MAPbI3) of about 10 µm grain size. Firstly, we demonstrate a direct spectral evidence of the large polarons in polycrystalline MAPbI3. Using the Drude-Smith-Lorentz model along with the FrÓ§hlich-type electron-phonon (e-ph) coupling, we determine the effective mass and scattering parameters of photogenerated polaronic carriers. We discover that the resulting moderate polaronic carrier mobility is mainly influenced by the enhanced carrier scattering, rather than the polaron mass enhancement. While, the formation of large polarons in MAPbI3 polycrystalline grains results in a long charge carrier lifetime at room temperature. Our results provide crucial information about the photo-physics of MAPbI3 and are indispensable for optoelectronic device development with better performance.

Measuring heavy metal ions in water using nature existed microalgae as medium based on terahertz technology.

Heavy metal pollution in water seriously affects human health. The disadvantages of traditional metal ion detection methods involve long and cumbersome chemical pretreatment in the early stage, and large volume of samples. In this study, microalgae were used as the medium, and terahertz spectroscopy technology was employed to collect the changes of material components in it, so as to deduce the types and concentrations of heavy metal pollution in water. Through the partial least square(PLS), we establish the prediction model of heavy metal concentration, and the results show that the best detection time for Pb2+ is 6 h and Ni2+ is 18 h. The principal component analysis(PCA) shows that ß-carotene is the most affected substance. Afterward we collect five real surface waters in East China and verify that the judgment accuracy of Pb2+ and Ni2+ are 100% and 93.2% respectively. The results indicate that the time is shorter than the traditional pretreatment time from more than 20-6 h, the sample volume is reduced from 50 mL to 10 mL, the detection accuracy is improved from 10 ng/mL to 1 ng/mL. In a word, we provide a new fast and real-time method for biological monitoring of heavy metal pollution in water.

Tunable Transmissive Terahertz Linear Polarizer for Arbitrary Linear Incidence Based on Low-Dimensional Metamaterials.

In this work, we propose a structure consisting of three metamaterial layers and a metallic grating layer to rotate the polarization of arbitrary linearly polarized incidence to the y-direction with high transmissivity by electrically tuning these metamaterials. The transfer matrix method together with a harmonic oscillator model is adopted to theoretically study the proposed structure. Numerical simulation based on the finite difference time-domain method is performed assuming that the metamaterial layers are constituted by graphene ribbon arrays. The calculation and simulation results show that the Drude absorption is responsible for the polarization rotation. Fermi level and scattering rate of graphene are important for the transmissivity. For a polarization rotation of around 90°, the thickness of either the upper or lower dielectric separations influences the transmission window. For a polarization rotation of around 45° and 135°, the lower dielectric separations decide the frequency of the transmission window, while the upper dielectric separations just slightly influence the transmissivity.

Malignant and benign thyroid nodule differentiation through the analysis of blood plasma with terahertz spectroscopy.

The liquid and lyophilized blood plasma of patients with benign or malignant thyroid nodules and healthy individuals were studied by terahertz (THz) time-domain spectroscopy and machine learning. The blood plasma samples from malignant nodule patients were shown to have higher absorption. The glucose concentration and miRNA-146b level were correlated with the sample's absorption at 1 THz. A two-stage ensemble algorithm was proposed for the THz spectra analysis. The first stage was based on the Support Vector Machine with a linear kernel to separate healthy and thyroid nodule participants. The second stage included additional data preprocessing by Ornstein-Uhlenbeck kernel Principal Component Analysis to separate benign and malignant thyroid nodule participants. Thus, the distinction of malignant and benign thyroid nodule patients through their lyophilized blood plasma analysis by terahertz time-domain spectroscopy and machine learning was demonstrated.

Terahertz spectroscopy of diabetic and non-diabetic human blood plasma pellets.

SIGNIFICANCE: The creation of fundamentally new approaches to storing various biomaterial and estimation parameters, without irreversible loss of any biomaterial, is a pressing challenge in clinical practice. We present a technology for studying samples of diabetic and non-diabetic human blood plasma in the terahertz (THz) frequency range. AIM: The main idea of our study is to propose a method for diagnosis and storing the samples of diabetic and non-diabetic human blood plasma and to study these samples in the THz frequency range. APPROACH: Venous blood from patients with type 2 diabetes mellitus and conditionally healthy participants was collected. To limit the impact of water in the THz spectra, lyophilization of liquid samples and their pressing into a pellet were performed. These pellets were analyzed using THz time-domain spectroscopy. The differentiation between the THz spectral data was conducted using multivariate statistics to classify non-diabetic and diabetic groups' spectra. RESULTS: We present the density-normalized absorption and refractive index for diabetic and non-diabetic pellets in the range 0.2 to 1.4 THz. Over the entire THz frequency range, the normalized index of refraction of diabetes pellets exceeds this indicator of non-diabetic pellet on average by 9% to 12%. The non-diabetic and diabetic groups of the THz spectra are spatially separated in the principal component space. CONCLUSION: We illustrate the potential ability in clinical medicine to construct a predictive rule by supervised learning algorithms after collecting enough experimental data.

Terahertz Broadband Polarization Conversion for Transmitted Waves Based on Graphene Plasmon Resonances.

We applied the harmonic oscillator model combined with the transfer matrix method to study the polarization conversion for transmitted waves in metallic grating/plasmon-excitation layer/metallic grating structure in the terahertz (THz) region. By comparing the calculated spectra and the simulated (by the finite-difference-time-domain method) ones, we found that they correspond well with each other. Both methods show that the Drude background absorption and the excited plasmon resonances are responsible for polarization conversion. The transmission is close to 0 when the distance between the top/bottom metallic gratings and gated graphene is an integer multiple of half the wavelength of the incident wave (in the dielectrics), at which points the plasmon resonances are greatly suppressed by the destructive interference between the backward/forward electromagnetic waves and that reflected by the top/bottom metallic gratings. Away from these points, the transmission can be higher than 80%. The electron density and the excitation efficiency of the plasmon-excitation layer were found to be important for the bandwidth of the polarization conversion window, while the scattering rate was found to influence mainly the polarization conversion rate. Multi-broadband polarization conversion is realized by exciting plasmon modes between the 0 transmission points in the THz region.

Geometry phase for generating multiple focal points with different polarization states.

Conventional lenses are always large and bulky to achieve desired wave-manipulating functions, hindering the development of integrated and miniaturized optical systems. Metasurfaces, two-dimensional counterparts of metamaterials, can accurately tailor the wavefront of electromagnetic waves at subwavelength scale, providing a flexible platform for designing ultra-compact and ultra-flat lenses, namely as metalenses. However, the previous geometry-phase-based metalenses usually generate focal point(s) with only one special polarization state, i.e., either linearly-polarized (LP) state or circularly-polarized (CP) state, which inevitably degrades further applications. Here, we propose and experimentally demonstrate an approach for designing terahertz (THz) metalenses based on geometry phase that can generate multiple focal points with different polarization states. Under the illumination of LP THz waves, three focal points with left-hand CP (LCP), right-hand CP (RCP) and LP states are observed. Furthermore, the position of each focal point can be flexibly manipulated in free space. Geometry metasurfaces consisting of micro-rods with the same shape but different in-plane orientations are fabricated to demonstrate these properties. This unique approach may enable an unprecedented capability in designing multifunctional THz devices with potential applications in imaging, detecting and communications.

Excitation of graphene surface plasmons polaritons by guided-mode resonances with high efficiency.

An Otto-like configuration for the excitation of graphene surface plasmon polaritons (GSPPs) is proposed. The configuration is composed of a metallic grating-dielectric-waveguide structure and a monolayer graphene with a subwavelength vacuum gap between them. The evanescent field located at the bottom surface of the dielectric waveguide corresponding to grating-coupled guided-mode resonances (GMRs) is utilized to efficiently excite the highly confined GSPPs. The finite difference time domain method is used to investigate the behaviors of the GMR-GSPP hybrid modes. The dispersion relations of GMRs and GSPPs are calculated and the numerical results further identify the excitation of GMR-GSPP hybrid modes. By changing the gap between the graphene layer and the bottom of the dielectric waveguide and the Fermi energy of graphene, the resonant frequencies of GMR-GSPP hybrid modes can be continuously tuned. When the optimized excitation condition is satisfied, the maximum energy enhancement factor in the gap can reach about 500 at the resonant frequencies. The proposed structure can be used to realize highly sensitive, compatible with planar fabrication technology, and electrically (mechanically) tunable sensors.

Terahertz-frequency temporal differentiator enabled by a high-Q resonator.

Terahertz (THz) fundamental "building blocks" equivalent to those used in multi-functional electronic circuits are very helpful for actual applications in THz data-processing technology and communication. Here, we theoretically and experimentally demonstrate a THz temporal differentiator based on an on-chip high-quality (Q) factor resonator. The resonator is made of low-loss high-resistivity silicon material in a monolithic, integrated platform, which is carefully designed to operate near the critical coupling region. The experiment demonstrates that the device can perform the first-order time derivative of the input signal electric field complex envelope at 214.72 GHz. Our investigation provides an effective approach for terahertz pulse re-shaping and real-time differential computing units.

Multiband and broadband active controllable terahertz absorption in dual-side grating-gate graphene field-effect transistors.

We show that the even order ungated modes can be excited under normal incidence while the odd order ungated modes cannot in traditional single-side grating-gate graphene field-effect transistors. The odd order ungated modes will suppress the excitation efficiency of the gated modes. In order to realize multiband detection by effectively exciting the higher order gated modes, the frequency of the 1st order ungated mode should be tuned up, which can be realized by shortening the length of the ungated region. We propose to use the dual-side grating-gate structure to shorten the length of the ungated region. Gated mode up to 21st order can be realized in complementary dual-side grating-gate structure. The ultra-multiband absorption can be actively controlled to cover 1.06-10 THz when the graphene Fermi energy is tuned from 0.2 eV to 0.6 eV. Even order gated modes will be excited by gradually overlapping the two grating layers because of the break of symmetry. Broadband detection from 0.1-8.2 THz can be realized by the effective excitation and overlap of the odd and even order gated modes.

Metal-graphene hybridized plasmon induced transparency in the terahertz frequencies.

In this work, metal-graphene hybridized plasmon induced transparency (PIT) is systematically studied in the proposed simple metal/dielectric/graphene system. The PIT effect is the result of the coupling between the bright dipolar modes excited in the graphene regions under the shorter metallic bars and the dark quadrupolar modes excited in the graphene regions under the longer metallic bars. The coupled Lorentz oscillator model is used to help explain the physical origin of the PIT effect. Other than being tuned by the distance and the lateral displacement of the orthogonal metallic bars, the coupling efficiency can be further enhanced by the in-phase coupling or quenched by the out-of-phase coupling between the adjacent unit cells. Reduced barrier thickness will result in the enhancement of the coupling strengths and the scaling down of the device. Finally, we show that the PIT window can be actively tuned by changing the Fermi energy of graphene. The proposed structure has potential applications in actively tunable THz modulators, sensors and filters.

"Terhune-like" transformation of the terahertz polarization ellipse "mutually induced" by three-wave joint propagation in liquid.

In this Letter, we show experimentally for the first time, to the best of our knowledge, the possibility to observe the effect of polarization mutual action of three elliptically polarized waves, with one of them at terahertz frequency, when they propagate in the isotropic nonlinear medium. When three light pulses are propagated at frequencies ω, 2ω, and ωTHz through liquid nitrogen, we observed the rotation of the ellipse main axis and the ellipticity change. We have shown that this effect is very well described theoretically in the framework of a physical approach analogous to the self-rotation of the polarization ellipse first described in 1964 by Maker et al., but expanded for the case of multi-frequency interaction.

Nitroxoline Molecule: Planar or Not? A Story of Battle between π-π Conjugation and Interatomic Repulsion.

The conformational properties of the nitro group in nitroxoline (8-hydroxy-5-nitroquinoline, NXN) were investigated in the gas phase by means of gas electron diffraction (GED) and quantum chemical calculations, and also with solid-state analysis performed using terahertz time-domain spectroscopy (THz-TDS). The results of the GED refinement show that in the equilibrium structure the NO2 group is twisted by angle ϕ = 8 ± 3° with respect to the 8-hydroxyoquinoline plane. This is the result of interatomic repulsion of oxygen in the NO2 group from the closest hydrogen, which overcomes the energy gain from the π-π conjugation of the nitro group and aromatic system of 8-hydroxyoquinoline. The computation of equilibrium geometry using MP2/cc-pVXZ (X = T, Q) shows a large overestimation of the ϕ value, while DFT with the cc-pVTZ basis set performs reasonably well. On the other hand, DFT computations with double-ζ basis sets yield a planar structure of NXN. The refined potential energy surface of the torsion vibration the of nitro group in the condensed phase derived from the THz-TDS data indicates the NXN molecule to be planar. This result stays in good agreement with the previous X-ray structure determination. The strength of the π-system conjugation for the NO2 group and 8-hydroxyoquinoline is discussed using NBO analysis, being further supported by comparison of the refined semiexperimental gas-phase structure of NXN from GED with other nitrocompounds.

Impact of the dipole contribution on the terahertz emission of air-based plasma induced by tightly focused femtosecond laser pulses.

The present paper studies the generation mechanism of terahertz (THz) radiation from tightly focused femtosecond laser pulses in a gas medium. We measured the angular radiation pattern under different focusing conditions and observed that, with the deepening of focus, the angular radiation pattern changes and optical-to-THz conversion efficiency increases. The analysis of the observed phenomena led to the assumption that the dipole radiation prevails in most cases despite the existing conception regarding the dominating role of the quadrupole mechanism of radiation. Based on these assumptions, the transient photocurrent theory of the phenomenon presented in this paper was developed by us and used for the numerical fit of the experimental data.

Possibility of direct estimation of terahertz pulse electric field.

In this Letter, we introduce a new method of estimation of the terahertz (THz) field amplitude. This method uses second-harmonic generation (SHG) in the presence of THz and DC fields in gaseous media. We take into account contributions from both nonionized molecules and free plasma electrons to the nonlinear process of SHG. We analyze the applicability of this method of detection to obtaining correct information on the waveform and amplitude of broadband THz pulses.

Design rules for phase-matched terahertz surface electromagnetic wave generation by optical rectification in a nonlinear planar waveguide.

The theory of guided waves in metal-dielectric planar multilayer structures is applied to reduce the loss and maximize optical nonlinearity for efficient terahertz-field generation in a surface electromagnetic wave by femtosecond laser pulses confined in a (chi)((2)) nonlinear planar waveguide. For typical parameters of thin-film polymer waveguides and metal-dielectric interfaces, the optimal size of the (chi)((2)) waveguide core providing the maximum efficiency of terahertz plasmon-field generation is shown to be less than the wavelength of the optical pump field.